tertiary-substituted arsonium mixed ligand salts

Author: Nino Muradashvili
Keywords: mixed ligands complexes arsonium acid
Annotation:

One of the most important properties of tertiary-substituted arsonium salts with the difference of cations represents inclination to forming the coordination compounds. They can construct cationic-anionic complexes in the alcohol-water solutions. The novelty is in the following: without educing the outlet of arsonium nitrates in the individual condition and by the interaction of cadmium iodate(v) the coordination compounds of [R 2 As(R)CH 2 I][Cd(IO 3 ) 2 CN] composition are received. It was established that the spatial arrangement of ligands into the anions and thus hybridization of electronic orbitals of cadmium is stipulated by existence of ligands of iodated-ions. The pormation of cyanide admixture of mixed ligand arsonium and purity was established by physical and chemical research methods.